Low Sulfate Seawater Injection for Barium Sulfate Scale Control: A Life-of-Field Solution to a Complex Challenge
- Myles M. Jordan (Nalco Co.) | Ian R. Collins (BP Exploration) | Eric J. Mackay (Heriot-Watt U.)
- Document ID
- Society of Petroleum Engineers
- SPE Production & Operations
- Publication Date
- May 2008
- Document Type
- Journal Paper
- 192 - 209
- 2008. Society of Petroleum Engineers
- 4.3 Flow Assurance, 4.5.10 Remotely Operated Vehicles, 5.1 Reservoir Characterisation, 6.5.2 Water use, produced water discharge and disposal, 3 Production and Well Operations, 4.5 Offshore Facilities and Subsea Systems, 1.6.9 Coring, Fishing, 5.3.1 Flow in Porous Media, 2.4.6 Frac and Pack, 4.2 Pipelines, Flowlines and Risers, 4.3.4 Scale, 1.6 Drilling Operations, 5.7.5 Economic Evaluations, 1.3.2 Subsea Wellheads, 4.5.4 Mooring Systems, 7.5.3 Professional Registration/Cetification, 1.14 Casing and Cementing, 5.8.8 Gas-condensate reservoirs, 5.4.1 Waterflooding, 4.3.1 Hydrates, 4.1.2 Separation and Treating, 5.5 Reservoir Simulation, 5.1.5 Geologic Modeling, 3.2.6 Produced Water Management, 4.2.4 Risers, 5.8.7 Carbonate Reservoir, 4.5.3 Floating Production Systems, 2.4.5 Gravel pack design & evaluation, 2.4.3 Sand/Solids Control, 7.2.1 Risk, Uncertainty and Risk Assessment, 1.8 Formation Damage, 2.2.2 Perforating, 1.2.3 Rock properties, 4.1.5 Processing Equipment, 4.2.3 Materials and Corrosion, 5.2 Reservoir Fluid Dynamics
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The injection of seawater into oil-bearing reservoirs to maintain reservoir pressure and improve secondary recovery is a well-established, mature operation. Moreover, the degree of risk posed by deposition of mineral scales to the injection and production wells during such operations has been much studied. The current deep water subsea developments offshore West Africa and Brazil have brought into focus the need to manage scale in an effective way. To this end, the challenge of scale control during the lifecycle of water injection, production, and onto produced water reinjection has been reviewed for a number of fields by the authors.
This outlines the risk assessment process that should be undertaken to select the most economical and effective scale control methodology (which for sulfate-based scale could be seawater injection with scale inhibitor squeeze treatments to maintain production, or sulfate reduction of the injection water with or without the need to scale inhibitor squeeze). In the case of sulfate reduction, parameters to be investigated include the degree of desulfation required to minimize the scale risk of downhole scale formation, the impact the degree of fluid mixing will have on the resulting brine (from injection to production), and the impact the desulfated brine will have on scale control during produced water reinjection.
The paper draws on a wide range of technical inputs to make scale management decisions including: computer modeling techniques (e.g., deposition models that incorporate the kinetics of sulfate scale formation at low supersaturation ratios), reservoir simulation of fluid mixing and reaction; the resulting produced brine chemistry, laboratory-generated coreflood data to assess chemical selection for scale inhibitor squeeze and produced water application; and field results that will demonstrate the impact of the type of injection water source on the long-term manageability of such deepwater projects. Finally, the paper outlines in detail the particular issues associated with the full economic assessment of low-sulfate water injection vs. full sulfate seawater injection.
After a brief overview of locations where oilfield scale can form and how it may change in composition throughout the life cycle, this paper discusses the factors that influence the choice of injection water, the impact of sulfate levels on scale control costs, and the scale risk assessment process that can be used to select the correct scale management strategy for economic field development.
Where Does Oilfield Scale Form?
The scaling reaction depends on there being sufficient concentrations of sulfate ions in the injected seawater, and barium, strontium and/or calcium-divalent cations in the formation brine to generate sulfate scale; or on sufficient bicarbonate and calcium ions to allow the formation of carbonate should the physical conditions result in a change in equilibrium. Thus, scale precipitation may occur wherever there is mixing of incompatible brines, or there are changes in the physical condition (such as pressure decline). An overview of all the possible scale formation environments for seawater, aquifer, natural depletion, and produced water reinjection is presented in Fig. 1.
- For example, before injection, if seawater injection is supplemented by produced water reinjection (PWRI)
- Around the injection well, as injected brine enters the reservoir contacting formation brine
- Deep in the formation, owing to displacement of formation brine by injected brine, or owing to converging flow paths
- As injection and formation brines converge towards the production well, but beyond the radius of a squeeze treatment
- As injection and formation brines converge towards the production well, and within the radius of a squeeze treatment
- In the completed interval of a production well, as one brine enters the completion, while another brine is flowing up the tubing from a lower section, or as fluid pressure decreases
- At the junction of a multilateral well, where one branch is producing a single brine and the other branch is producing incompatible brine
- At a subsea manifold, where one well is producing one brine and another well is producing a different brine
- At the surface facilities, where one production stream is flowing one brine and another production stream is flowing another brine
- During aquifer water production and processing for reinjection, with the possibility of scale formation within a self-scaling brine or mixing with an incompatible formation brine as in b)
- During pressure reduction and/or an increase in temperature within any downhole tubing or surface processing equipment, leading to the evolution of CO2 and to the generation of carbonate and sulfide scale if the appropriate ions are present. Temperature reduction could lead to the formation of halite scales if the brine is close to saturation under reservoir conditions.
|File Size||5 MB||Number of Pages||18|
Andersen, K.I., Halvorsen, E., Sælensminde, T., and Østbye, N.O. 2000. Water Management in a ClosedLoop—Problems and Solutions at Brage Field. Paper SPE 65162 presented atthe SPE European Petroleum Conference, Paris, 24-25 October. doi:10.2118/65162-MS
Collins, I.R. 2002. A New Modelfor Mineral Scale Adhesion. Paper 74655 presented at the SPE InternationalSymposium on Oilfield Scale, Aberdeen, 30-31 January. doi: 10.2118/74655-MS
Collins, I.R. 2003. Scale Management and Risk Assessment for DeepwaterDevelopments. World Oil 224 (5): 62-69.
Collins, I.R. 2005. Predictingthe Location of Barium Sulfate Scale Formation in Production Systems. PaperSPE 94366 presented at the SPE International Symposium on Oilfield Scale,Aberdeen, 11-12 May. doi: 10.2118/94366-MS
Collins, I.R. and Jordan, M.M. 2001. Occurrence, Prediction and Preventionof Zinc Sulfide Scale Within Gulf Coast and North Sea High Temperature/HighSalinity Production Wells. Paper SPE 68317 presented at the SPEInternational Symposium on Oilfield Scale, Aberdeen, 30-31 January. doi:10.2118/68317-MS
Davis, R., Lomax, I., and Plummer, M. 1996. Membranes Solve North SeaWaterflood Sulfate Problems. Oil & Gas J. 25 November, 59-64.
Emmons, D.H. and Jordan, M.M. 1999. The Development of Near-Real TimeMonitoring of Scale Deposition. Presented at the SPE Oilfield Scale Symposium,Aberdeen, 27-28 January.
Emmons, D.H., Graham, G.C., Holt, S.P., Jordan, M.M., and Locardel, B. 1999.On-Site, Near-Real-Time Monitoringof Scale Deposition. Paper SPE 56776 presented at the SPE Annual TechnicalConference and Exhibition, Houston, 3-6 October. doi: 10.2118/56776-MS
Evans, R. 2000. Decision Analysis for Integrated Oilfield Scale Studies.Paper SPE 60213 presented at the SPE International Symposium on Oilfield Scale,Aberdeen, 26-27 January.
Feasey, N.D., Wintle, R.J., Frieter, E.R., and Jordan, M.M. 2000. FieldExperience With a Novel Near Real Time Monitor for Scale Deposition in OilfieldSystem. NACE 2000, Orlando Florida, 26-31 March.
Graham, G.M. and Collins, I.R. 2004. Assessing Scale Risks andUncertainties for Subsea and Marginal Field Developments. Paper SPE 87460presented at the SPE International Symposium on Oilfield Scale, Aberdeen, 26-27May. doi: 10.2118/87460-MS
Hardy, J.A. and Simm, I. 1996. Low Sulfate Seawater Mitigates Barite Scale.Oil & Gas J. 2 December.
Hjelmas, T.A., Bakke, S., Hilde, T., Vik, E.A., and Gruner, H. 1996. Produced Water Reinjection:Experiences From Performance Measurements on Ula in the North Sea. PaperSPE 35874 presented at the SPE Health, Safety and Environment in Oil and GasExploration and Production Conference, New Orleans, 9-12 June. doi:10.2118/35874-MS
Jordan, M.M., Archibald, I., Donaldson, L., Stevens, K., and Kemp, S. 2003.Deployment, Monitoring andOptimisation of Combined Scale/Corrosion Inhibitor Within a Subsea Facility inthe North Sea Basin. Paper SPE 80214 presented at the SPE Symposium onOilfield Chemistry, Houston, 5-7 February. doi: 10.2118/80214-MS
Jordan, M.M., Buckman, J., and Johnston, C.J. 2005. Direct Monitoring of the Performanceof Scale Control Programs Across the Produced Water Life Cycle via SuspendedSolids Analysis. Paper SPE 93892 presented at the SPE European FormationDamage Conference, Scheveningen, The Netherlands, 25-27 May. doi:10.2118/93892-MS
Jordan, M.M., Sjuraether, K., Collins, I.R., Feasey, N.D., and Emmons, D.2001. Life Cycle Management ofScale Control Within Subsea Fields and Its Impact on Flow Assurance, Gulf ofMexico and the North Sea Basin. Paper SPE 71557 presented at the SPE AnnualTechnical Conference and Exhibition, New Orleans, 30 September-3 October. doi:10.2118/71557-MS
Jordan, M.M., Sjursaether, K., Edgerton, M.C., and Bruce R. 2000. Inhibition of Lead and Zinc SulfideScale Deposits Formed During Production From High Temperature Oil andCondensate Reservoirs. Paper SPE 64427 presented at the SPE Asia PacificOil and Gas Conference and Exhibition, Brisbane, Australia, 16-18 October. doi:10.2118/64427-MS
Mackay, E.J. 2003. Modeling ofIn-Situ Scale Deposition: The Impact of Reservoir and Well Geometries andKinetic Reaction Rates. SPEPF 18 (1): 45-56. SPE-81830-PAdoi: 10.2118/81830-PA
Mackay, E.J. and Graham, G.M. 2003. The Use of Flow Models in Assessingthe Risk of Scale Damage. Paper SPE 80252 presented at the SPEInternational Symposium on Oilfield Chemistry, Houston, 5-7 February. doi:10.2118/80252-MS
Mackay, E.J. and Jordan, M.M. 2003. Natural Sulfate Ion Stripping DuringSeawater Flooding in Chalk Reservoirs. RSC Chemistry in the Oil Industry VIIIConference, Manchester, U.K., 3-5 November.
Mackay, E.J. et al. 2005. Integrated Risk Analysis for ScaleManagement in Deepwater Developments. Paper SPEPF 20 (2):138-154. SPE-87459-PA doi: 10.2118/87459-PA
Mackay, E.J., Collins, I.R., Jordan, M.M., and Feasey, N. 2003a. PWRI: Scale Formation Risk Assessmentand Management. Paper SPE 80385 presented at the SPE InternationalSymposium on Oilfield Scale, Aberdeen, 29-30 January. doi: 10.2118/80385-MS
Mackay, E.J., Jordan, M.M., and Torabi, F. 2003b. Predicting Brine Mixing Deep Withinthe Reservoir, and Its Impact on Scale Control in Marginal and DeepwaterDevelopments. SPEPF 18 (3): 210-220. SPE-85104-PA doi:10.2118/85104-PA
Martins, J.P. et al. 1995. Produced-Water Reinjection andFracturing in Prudhoe Bay. SPERE 10 (3): 176-182;Trans., SPE, 299. SPE-28936-PA doi: 10.2118/28936-PA
Paige, R.W. and Sweeney, F.M. 1993. Produced Water-Reinjection:Understanding the Problems. Water Management Offshore Conference, Aberdeen, 6-7October.
Simpson, A.J. and Paige, R.W. 1991. Advances in Forties Field WaterInjection. Paper SPE 23140 presented at SPE Offshore Europe, Aberdeen, 3-6September. doi: 10.2118/23140-MS
Sorbie, K.S. and Mackay, E.J. 2000. Mixing of Injected,Connate and Aquifer Brines in Waterflooding and Its Relevance to OilfieldScaling. Journal of Petroleum Science and Engineering 27(1-2): 85-106. doi: 10.1016/S0920-4105(00)00050-4.
Vu, V.K., Hurtevent, C., and Davis, R.A. 2000. Eliminating the Need for ScaleInhibition Treatments for Elf Exploration Angola's Girassol Field. PaperSPE 60220 presented at the SPE International Symposium on Oilfield Scale,Aberdeen, 26-27 January. doi: 10.2118/60220-MS
Wattie, I., Wolf, N., and Graham, G.M. 2002. Decision Analysis Applied toOilfield Scale Treatment. Paper SPE 74671 presented at the SPE Oilfield ScaleSymposium, Aberdeen, 30-31 January.