Sorption Study of ?-AlO(OH) Nanoparticle-Crosslinked Polymeric Scale Inhibitors and Their Improved Squeeze Performance in Porous Media
- Chao Yan (Rice University) | Amy T. Kan (Rice University) | Wei Wang (Rice University) | Fei Yan (Rice University) | Lu Wang (Rice University) | Mason B. Tomson (Rice University)
- Document ID
- Society of Petroleum Engineers
- SPE Journal
- Publication Date
- August 2014
- Document Type
- Journal Paper
- 687 - 694
- 2014.Society of Petroleum Engineers
- 4.1.2 Separation and Treating, 4.3.4 Scale
- squeeze treatment, porous media, polymeric scale inhibitor, crosslinked, nanoparticles
- 2 in the last 30 days
- 338 since 2007
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Polymeric scale inhibitors are widely used in the oil and gas field because of their enhanced thermal stability and better environmental compatibility. However, the squeeze efficiency of such threshold inhibitors, not only polymeric scale inhibitors but also phosphonates, is typically poor in conventional squeeze treatment. In this research, nanoparticle (NP)-crosslinked polymeric scale inhibitors were developed for scale control. Nearly monodispersed boehmite [γ-AlO(OH)] NPs with average size of 2.8 nm were synthesized and used to crosslink sulfonated polycarboxylic acid (SPCA). Crosslinked AlO(OH)-SPCA nanoinhibitors were produced and developed to increase the retention of SPCA in formations by converting liquid-phase polymeric scale inhibitors into a viscous gel. Study of sorption of SPCA onto AlO(OH) NPs under different pHs with and without assistance of Ca2+ was discussed. In addition, study of sorption of various types of scale inhibitors [SPCA; phosphino-polycarboxylic acid (PPCA); and diethylenetriaminepentatakis(methylene phosphonic acid) (DTPMP)] onto AlO(OH) NPs was performed. Squeeze simulation of neat 3% SPCA, AlO(OH) (3%)-SPCA (3%) NPs, and AlO(OH) (3%)-SPCA (3%)-Ca NPs was investigated. The results showed that the addition of Ca2+ ions improves the squeeze performance of SPCA, and the normalized squeeze life (NSL) of such material (8,952 bbl/kg) was improved by a factor greater than 60 compared with that of SPCA alone (152 bbl/kg).
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Collins, I.R., Cowie, L.G., Micol, M., et al. 1999. Field Application of a Scale Inhibitor Squeeze Enhancing Additive. SPE Prod & Fac 14 (1): 21–29. http://dx.doi.org/10.2118/54525-PA/.
Dickinson, W., Griffin, R., Sanders, L., et al. 2011. Development and Performance of Biodegradable Antiscalants for Oilfield Applications. Paper SPE 21788 presented at the Offshore Technology Conference, Houston, Texas, 2–5 May. http://dx.doi.org/10.4043/21788-MS.
Fan, C.F., Shi, W., Zhang, P., et al. 2011. Ultrahigh-Temperature/Ultrahigh-Pressure Scale Control for Deepwater Oil and Gas Production. SPE J. 17 (1): 177–186. http://dx.doi.org/10.2118/141349-PA.
Friedfeld, S. J., He, S., Tomson, M.B. 1998. The Temperature and Ionic Strength Dependence of the Solubility Product Constant of Ferrous Phosphonate. Langmuir 14: 3698–3703. http://dx.doi.org/10.1021/la971293l.
Frostman, L. M., Kan, A.T., Tompson, M.B. 1998. Mechanistic Aspects of Calcium Phosphonates Precipitation. In Calcium Phosphates in Biological and Industrial Systems, ed. Z. Amjad, Chap. 22, 493–506. Boston, Massachusetts: Kluwer Academic Publishers.
He, S.; Oddo, J. E. and Tomson, M. B. 1994. The Inhibition of Gypsum and Barite Nucleation in NaCl Brines at Temperature from 25 to 90°C. Appl. Geochem. 9 (5): 561–567. http://dx.doi.org/10.1016/0883-2927(94)90018-3.
Graham, G.M., Dyer, S.J., Sorbie, K.S., et al. 1998. Scale Inhibitor Selection for Continuous and Downhole Squeeze Application in HP/HT Conditions. Paper SPE 49197 presented at the SPE Annual Technical Conference and Exhibition, New Orleans, Louisiana, 27–30 September. http://dx.doi.org/10.2118/49197-MS.
Gupta, D.V.S., Brown, M. and Szymczak, S. 2008. Multi-Year Scale Inhibition from a Solid Inhibitor Applied during Stimulation. Paper SPE 115655 presented at the SPE Annual Technical Conference and Exhibition, Denver, Colorado, 21–24 September. http://dx.doi.org/10.2118/115655-MS.
Heath, S.M., Sim, M., Archibald, M., et al. 2008. Development of a Viscosified Scale Inhibitor for Improving Placement in Acid Fractured Limestone Reservoirs. Paper SPE 114046 presented at the SPE International Oilfield Scale Conference, Aberdeen, Scotland, UK, 28–29 May. http://dx.doi.org/10.2118/114046-MS.
James, J.S., Frigo, D.M., Townsend, M.M., et al. 2005. Application of a Fully Viscosified Scale Squeeze for Improved Placement in Horizontal Wells. Paper SPE 94593 presented at the SPE International Symposium on Oilfield Scale, Aberdeen, Scotland, UK, 11–12 May. http://dx.doi.org/10.2118/94593-MS.
Jordan, M. M., Sorbie, K. S., Griffin, P., et al. 1995. Scale Inhibitor Adsorption/Desorption vs. Precipitation: The Potential for Extending Squeeze Life While Minimising Formation Damage. Paper SPE 30106 presented at the SPE European Formation Damage Conference, The Hague, the Netherlands, 15–16 May. http://dx.doi.org/10.2118/30106-MS.
Kan, A. T., Fu, G., Alsalari, H. A., et al. 2009. Enhanced Scale-Inhibitor Treatments With the Addition of Zinc. SPE J. 14 (4): 617–626. http://dx.doi/org/10.2118/114060-PA.
Kan, A. T., Fu, G. and Tomson, M. B. 2005. Adsorption and Precipitation of an Aminoalkylphosphonate onto Calcite. J. Colloid Interf. Sci. 281 (2): 275–284. http://dx.doi.org/10.1016/j.jcis.2004.08.054.
Kan, A. T., Fu, G. and Tomson, M. B. 2004. Factors Affecting Scale Inhibitor Retention in Carbonate-Rich Formation During Squeeze Treatment. SPE J. 9 (3): 280–239. http://dx.doi.org/10.2118/80230-PA.
Kan, A. T., Oddo, J. E. and Tomson, M. B. 1994. Formation of Two Calcium Diethylenetriaminepentakis(methy1ene phosphonic acid) Precipitates and Their Physical Chemical Properties. Langmuir 10: 1450–1455. http://dx.doi.org/10.1021/la00017a022.
Kan, A. T. and Tomson, M. B. 2012. Scale Prediction for Oil and Gas Production. SPE J. 17 (2): 362–378. http://dx.doi.org/10.2118/132237-PA.
Kelland, M. A. 2006. Production Chemicals for the Oil and Gas Industry. Boca Raton, Florida: CRC Press.
Parks, G. A. 1965. The Isoelectric Points of Solid Oxides, Solid Hydroxides, and Aqueous Hydroxo Complex Systems. Chem. Rev. 65 (2): 177–198. http://dx.doi.org/10.1021/cr60234a002.
Perkin Elmer. 2011. Atomic Spectroscopy: A Guide to Selecting the Appropriate Technique and System, http://www.perkinelmer.com/PDFs/Downloads/BRO_WorldLeaderAAICPMSICPMS.pdf.
Powell, R.J., Gdanski, R.D., McCabe, M.A., et al. 1995. Controlled-Release Scale Inhibitor for Use in Fracturing Treatments. Paper SPE 28999 presented at the SPE International Symposium on Oilfield Chemistry, San Antonio, Texas, 14–17 February. http://dx.doi.org/10.2118/28999-MS.
Rosenstein, L. 1936. Process for Treating Water. US Patent No. 2038416.
Selle, O. M., Springer, M., Auflem, I. H., et al. 2009. Gelled Scale Inhibitor Treatment for Improved Placement in Long Horizontal Wells at Norne and Heidrun Fields. SPE Prod & Oper 24 (3): 425–438. http://dx.doi.org/10.2118/112464-PA.
Shen, D., Zhang, P., Kan, A. T., et al. 2008. Control Placement of Scale Inhibitors in the Formation with Stable Ca-DTPMP Nanoparticle Suspension and its Transport in Porous Media. Paper SPE 114603 presented at the SPE International Oilfield Scale Conference, Aberdeen, Scotland, UK, 28–29 May. http://dx.doi.org/10.2118/114063-MS.
Sorbie, K. S., Mackay, E. J., Collins, I. R., et al. 2006. Placement Using Viscosified Non-Newtonian Scale Inhibitor Slugs: The Effect of Shear Thinning. SPE Prod & Oper 22 (4): 434–441. http://dx.doi.org/10.2118/100520-PA.
Tomson, M. B., Kan, A. T. and Fu, G. 2006. Control of Inhibitor Squeeze Through Mechanistic Understanding of Inhibitor Chemistry. SPE J. 11 (3): 283–293. http://dx.doi.org/10.2118/87450-PA.
Wang, S.Y. and Wylde, J.J. 2009. Scale Inhibitor Selection for Deepwater High Temperature Applications. Paper NACE International 09278 presented at Corrosion 2009, Atlanta, Georgia, 22–26 March.
Wang, W., Kan, A.T. and Tomson, M.B. 2012. A Novel and Comprehensive Study of Polymeric and Traditional Phosphonate Inhibitors for High Temperature Scale Control. SPE J. 18 (3): 575–582. http://dx.doi.org/10.2118/155108-PA.
Watanabe, Y., Kasama, T., Fukushi, K., 2011. Synthesis of Nano-sized Boehmites for Optimum Phosphate Sorption. Separ. Sci. Tech. 46 (5): 818–824. http://dx.doi.org/10.1080/01496395.2010.535590.
Xiao, J., Kan, A. T. and Tomson, M. B. 2001. Acid-Base and Metal Complexation Chemistry of Phosphino-polycarboxylic Acid under High Ionic Strength and High Temperature. Langmuir 17 (15): 4661–4667. http://dx.doi.org/10.1021/la001720m.
Yan, C., Kan, A. T., Wang, W., et al. 2012. Synthesis and Size Control of Monodispersed Al-sulphonated Polycarboxylic Acid (Al-SPCA) Nanoparticles with Improved Squeeze Performance and Their Transport in Porous Media. Paper SPE 155267 presented at SPE International Oilfield Nanotechnology Conference, Noordwijk, The Netherlands, 12–14 June. http://dx.doi.org/10.2118/155627-MS.
Yan, C., Kan, A. T., Wang, W., et al. 2012. Boehmite Based Sulphonated Polymer Nanoparticles with ImprovedSqueeze Performance for Deepwater Scale Control. Paper OTC 24252 presented at 2013 Offshore Technology Conference, Houston, Texas, 6–9 May. http://dx.doi.org/10.4043/24252-MS.
Yoldas, B.E. 1975. Alumina Sol Preparation from Alkoxides. Ceram. Bull. 54 (3): 289–290.
Zhang, P., Fan, C., Lu, H., et al. 2011. Synthesis of Crystalline-Phase Silica-Based Calcium Phosphonate Nanomaterials and Their Transport in Carbonate and Sandstone Porous Media. Ind. Eng. Chem. Res. 50 (4): 1819–1830. http://dx.doi.org/10.1021/ie101439x.
Zhang, P., Kan, A. T., Fan, C., et al. 2011. Silica-Templated Synthesis of Novel Zinc-DTPMP Nanomaterials: Their Transport in Carbonate and Sandstone Media During Scale Inhibition. SPE J. 16 (3): 662–671. http://dx.doi.org/10.2118/130639-PA.
Zhang, P., Shen, D., Fan, C., et al. 2010. Surfactant-Assisted Synthesis of Metal-Phosphonate Inhibitor Nanoparticles and Transport in Porous Media. SPE J. 15 (3): 610–617. http://dx.doi.org/10.2118/121552-PA.