Residual-Oil Recovery Through Injection of Biosurfactant, Chemical Surfactant, and Mixtures of Both Under Reservoir Temperatures: Induced-Wettability and Interfacial-Tension Effects
- Hanaa Al-Sulaimani (Sultan Qaboos University) | Yahya Al-Wahaibi (Sultan Qaboos University) | Saif Al-Bahry (Sultan Qaboos University) | Abdulkadir Elshafie (Sultan Qaboos University) | Ali Al-Bemani (Sultan Qaboos University) | Sanket Joshi (Shiraz University)
- Document ID
- Society of Petroleum Engineers
- SPE Reservoir Evaluation & Engineering
- Publication Date
- April 2012
- Document Type
- Journal Paper
- 210 - 217
- 2012. Society of Petroleum Engineers
- 2.5.2 Fracturing Materials (Fluids, Proppant), 1.6.9 Coring, Fishing
- biosurfactant, wettability, adsorption, contact angle
- 4 in the last 30 days
- 1,093 since 2007
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In this study, a biosurfactant produced by a Bacillus subtilis strain isolated from oil-contaminated soil from an Omani oil field was tested for its potential in enhancing oil recovery by a series of coreflooding experiments. It was found that the performance of the biosurfactant was increased by mixing with chemical surfactants, by which the maximum production went up to 50% of residual oil at a mixing ratio of (50:50). The second objective of this study was to investigate the effects of the biosurfactant on wettability alteration and to estimate its tendency to loss caused by adsorption. The influence of biosurfactant on wettability was studied by contact-angle measurements, atomic force microscopy (AFM) technique on few-layer graphene (FLG) surfaces, and Amott wettability tests on Berea sandstone cores. Contact-angle measurements showed that the wettability of the biosurfactant solution changes to more oil-wet as the angle decreased from 70.6 to 25.32° when treated with 0.25% (w/v) biosurfactant solution. Amott testing showed a change in wettability index from strongly water-wet in the untreated core toward less water-wet in biosurfactant-treated cores. These results confirmed the ability of the biosurfactant to alter the wetting conditions against different surfaces, thereby serving as a mechanism for enhancing oil recovery. The maximum loss of biosurfactant caused by adsorption was 1.2 mg/g of rock, which is comparable with reported chemical-surfactant values.
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Afrapoli, M. S., Crescente, C. and Torsæter, O. 2008. Proc., 10thInternational Symposium on Evaluation of Wettability and Its Effect on OilRecovery, Abu Dhabi, UAE, 27-28 October.
Al-Sulaimani, H., Al-Wahaibi, Y., Al-Bahry, S., et al. 2011. Optimizationand Partial Characterization of Biosurfactants Produced by Bacillus Species andTheir Potential for Ex-Situ Enhanced Oil Recovery. SPE J. 16 (3): 672-682. SPE-129228-PA. http://dx.doi.org/10.2118/129228-PA.
Al-Sulaimani, H.S., Al-Wahaibi, Y.M., Al-Bahry, S., et al. 2010.Experimental Investigation of Biosurfactants Produced by Bacillus Species andtheir Potential for MEOR in Omani Oil Field. Paper SPE 129228 presented at theSPE EOR Conference at Oil & Gas West Asia, Muscat, Oman, 11-13 April. http://dx.doi.org/10.2118/129228-MS.
Alveskog, P.L., Holt, T., and Torsæter, O. 1998. The effect ofsurfactant concentration on the Amott wettability index and residual oilsaturation. J. Pet. Sci. Eng. 20 (3-4): 247-252. http://dx.doi.org/10.1016/S0920-4105(98)00027-8.
Anderson, W.G. 1986. Wettability Literature Survey--Part 2: WettabilityMeasurement. J Pet Technol 38 (11): 1246-1262.SPE-13933-PA. http://dx.doi.org/10.2118/13933-PA.
Aoudia, M., Al-Shibli, M., Al-Kasimi, L., Al-Maamari, R., and Al-Bemani, A. 2006. Novel surfactants for ultralow interfacial tension in awide range of surfactant concentration and temperature. J. SurfactantsDeterg. 9 (3): 287-293. http://dx.doi.org/10.1007/s11743-006-5009-9.
Austad, T. and Standnes, D.C. 2003. Spontaneous imbibition of water intooil-wet carbonates. J. Pet. Sci. Eng. 39 (3-4): 363-376. http://dx.doi.org/10.1016/s0920-4105(03)00075-5.
Babadagli, T. 2002. Dynamics of Capillary Imbibition When Surfactant,Polymer, and Hot Water Are Used as Aqueous Phase for Oil Recovery. J.Colloid Interface Sci. 246 (1): 203-213. http://dx.doi.org/10.1006/jcis.2001.8015.
Curbelo, F.D.S., Santanna, V.C., Neto, E.L.B., et al. 2007. Adsorption ofnonionic surfactants in sandstones. Colloids Surf., A 293(1-3): 1-4. http://dx.doi.org/10.1016/j.colsurfa.2006.06.038.
Daoshan, L., Shouliang, L., Yi, L., and Demin, W. 2004. The effect ofbiosurfactant on the interfacial tension and adsorption loss of surfactant inASP flooding. Colloids Surf., A 244 (1-3): 53-60. http://dx.doi.org/10.1016/j.colsurfa.2004.06.017.
Dehghan-Noudeh, G., Housaindokht, M., and Bazzaz, B.S.F. 2005.Isolation, characterization, and investigation of surface and hemolyticactivities of a lipopeptide biosurfactant produced by Bacillus subtilisATCC 6633. The Journal of Microbiology 43 (3): 272-276.
Gautam, K.K. and Tyagi, V.K. 2006. Microbial Surfactants: A Review. J.Oleo Sci. 55 (4): 155-166. http://dx.doi.org/10.5650/jos.55.155.
Ghojavand, H., Vahabzadeh, F., Roayaei, E., and Shahraki, A.K. 2008.Production and properties of a biosurfactant obtained from a member of theBacillus subtilis group (PTCC 1696). J. Colloid Interface Sci. 324 (1-2): 172-176. http://dx.doi.org/10.1016/j.jcis.2008.05.001.
Hazra, C., Kundu, D., Ghosh, P., Joshi, S., Dandi, N., and Chaudhari,A. 2011. Screening and identification of Pseudomonas aeruginosa AB4 forimproved production, characterization and application of a glycolipidbiosurfactant using low-cost agro-based raw materials. J. Chem. Technol.Biotechnol. 86 (2): 185-198. http://dx.doi.org/10.1002/jctb.2480.
Hirasaki, G. and Zhang, D.L. 2004. Surface Chemistry of Oil Recovery FromFractured, Oil-Wet, Carbonate Formation. SPE J. 9 (2): 151-162.SPE-88365-PA. http://dx.doi.org/10.2118/88365-PA.
Iglauer, S., Wu, Y., Shuler, P., Tang, Y., and Goddard Iii, W.A. 2010.New surfactant classes for enhanced oil recovery and their tertiary oilrecovery potential. J. Pet. Sci. Eng. 71 (1-2): 23-29. http://dx.doi.org/10.1016/j.petrol.2009.12.009.
Kowalewski, E., Rueslåtten, I., Steen, K.H., Bødtker, G., and Torsæter, O. 2006. Microbial improved oil recovery—bacterial inducedwettability and interfacial tension effects on oil production. J. Pet. Sci.Eng. 52 (1-4): 275-286.
Lee, S.-C., Kim, S.-H., Park, I.-H., Chung, S.-Y., and Choi,Y.-L. 2007. Isolation and structural analysis of bamylocin A, novel lipopeptidefrom Bacillus amyloliquefaciens LP03 having antagonistic and crudeoil-emulsifying activity. Arch. Microbiol. 188 (4):307-312. http://dx.doi.org/10.1007/s00203-007-0250-9.
Morrow, N.R. 1990. Wettability and Its Effect on Oil Recovery. J PetTechnol 42 (12): 1476-1484. SPE-21621-PA. http://dx.doi.org/10.2118/21621-PA.
Mu, B., Wu, Z., Chen, Z., Wang, X., Ni, F., and Zhou, J.2002. Wetting behavior on quartz surfaces by the microbial metabolism andmetabolic products. Paper presented at the International Symposium onWettability and Its Effects on Oil Recovery, Tasmania, Australia, 12-14March.
Portwood, J.T. 1995. A Commercial Microbial Enhanced Oil RecoveryTechnology: Evaluation of 322 Projects. Paper SPE 29518 presented at theProduction Operations Symposium, Oklahoma City, Oklahoma, USA, 2-4 April. http://dx.doi.org/10.2118/29518-MS.
Rosen, M.J. 2004. Surfactants and Interfacial Phenomena, thirdedition, 38. New York City: John Wiley & Sons.
Salehi, M., Johnson, S., Liang, J.-T., Fox, S., and Bala, G. 2006.Wettability alteration of carbonate rock mediated by biosurfactant producedfrom high-starch agricultural effluents. Paper A16 presented at the 9thInternational Wettability Symposium, Bergen, Norway, 18-19 September.
Sayyouh, M.H. and Al-Blehed, M.S. 1995. Effect of microorganisms on rockwettability. J. Adhes. Sci. Technol. 9: 425-431. http://dx.doi.org/10.1163/156856195x00365.
Singh, A., Van Hamme, J.D., and Ward, O.P. 2007. Surfactants inmicrobiology and biotechnology: Part 2. Application aspects. Biotechnol.Adv. 25 (1): 99-121. http://dx.doi.org/10.1016/j.biotechadv.2006.10.004.
Standnes, D.C. and Austad, T. 2000. Wettability alteration in chalk 2.Mechanism for wettability alteration from oil-wet to water-wet usingsurfactants. J. Pet. Sci. Eng. 28 (3): 123-143. http://dx.doi.org/10.1016/S0920-4105(00)00084-X.
Thomas, C.P., Bala, G.A., and Duvall, M.L. 1993. Surfactant-Based EORMediated by Naturally Occurring Microorganisms. SPE Res Eng 8(4): 285-291. SPE-22844-PA. http://dx.doi.org/10.2118/22844-PA.
Youssef, N., Simpson, D.R., Duncan, K.E., et al. 2007. In Situ BiosurfactantProduction by Bacillus Strains Injected into a Limestone Petroleum Reservoir.Appl Environ Microbiol 73 (4): 1239-1247. http://dx.doi.org/10.1128/aem.02264-06.
Zargari, S., Ostvar, S., Niazi, A., and Ayatollahi, S. 2010. AtomicForce Microscopy and Wettability Study of the Alteration of Mica and Sandstoneby a Biosurfactant-Producing Bacterium Bacillus thermodenitrificans. J. Adv.Microsc. Res. 5 (2): 143-148. http://dx.doi.org/10.1166/jamr.2010.1036.
Zekri, A.Y., Mamdouh, T.G., and Almehaideb, R.A. 2003. Carbonate RocksWettability Changes Induced by Microbial Solution. Paper SPE 80527 presented atthe SPE Asia Pacific Oil and Gas Conference and Exhibition, Jakarta, 15-17April. http://dx.doi.org/10.2118/80527-MS.
Zhang, P. and Austad, T. 2006. Wettability and oil recovery from carbonates:Effects of temperature and potential determining ions. Colloids Surf., A 279 (1-3): 179-187. http://dx.doi.org/10.1016/j.colsurfa.2006.01.009.
Zhu, Y., Xu, G., Gong, H., Wu, D., and Wang, Y. 2009. Production ofultra-low interfacial tension between crude oil and mixed brine solution ofTriton X-100 and its oligomer Tyloxapol with cetyltrimethylammonium bromideinduced by hydrolyzed polyacrylamide. Colloids Surf., A 332(2-3): 90-97. http://dx.doi.org/10.1016/j.colsurfa.2008.09.012.