Estimation of Potential Precipitation From an Equilibrated Calcium Carbonate Aqueous Phase Using Simple Predictive Tool
- Alireza Bahadori (Southern Cross University)
- Document ID
- Society of Petroleum Engineers
- SPE Projects, Facilities & Construction
- Publication Date
- December 2011
- Document Type
- Journal Paper
- 158 - 165
- 2011. Society of Petroleum Engineers
- 1.8 Formation Damage, 5.2 Reservoir Fluid Dynamics
- Saturation index, CO2 Sequestration, Scale, Calcium carbonate, Carbon dioxide
- 2 in the last 30 days
- 363 since 2007
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|SPE Non-Member Price:||USD 35.00|
Carbon dioxide (CO2) sequestration in saline aquifers has been proposed as one of the most practical options for reducing CO2 emissions into the atmosphere. Massive CO2 injection into an aquifer would alter the geochemical equilibrium between the rock-forming minerals and the formation water. In this work, a novel and simple predictive tool is presented to estimate the formation of calcium carbonate (CaCO3) scaling as a function of pH, temperature, ionic strength of the solution, calcium cation concentration, bicarbonate anion concentration, and CO2 mole fraction when the water mixture is saturated with a gas containing CO2 to evaluate the effect of solution conditions on the tendency and extent of precipitation. The proposed simple method covers concentrations of calcium cation or bicarbonate anion in the range of 10 to 10 000 mg/L, with temperature ranging between 5 and 90°C, total ionic strength ranging between 0.1 and 3.6, and pH values ranging between 5.5 and 8. The predicted values are found to be in good agreement with the reported data, with average absolute deviations being less than 2.6%. The proposed tool is superior because of its accuracy and clear numerical background based on the Vandermonde matrix, wherein the relevant coefficients can be retuned quickly if more data become available in the future. The simple predictive tool proposed in the paper can be of immense practical value for engineers and researchers to have a quick check on the formation of calcium carbonate scaling when the water mixture is saturated with a gas containing CO2 at various conditions without opting for any experimental measurements. In particular, process engineers would find the proposed method to be user friendly, involving no complex expressions and presenting transparent calculations.
|File Size||2 MB||Number of Pages||8|
Bachu, S., Bonijoly, D., Bradshaw, J., et al. 2007. CO2 storage capacityestimation: Methodology and gaps. Int. J. Greenhouse Gas Control 1 (4): 430-443. http://dx.doi.org/10.1016/s1750-5836(07)00086-2.
Bahadori, A. and Vuthaluru, H.B. 2009. New method accurately predicts carbondioxide equilibrium adsorption isotherms. Int. J. Greenhouse Gas Control 3 (6): 768-772. http://dx.doi.org/10.1016/j.ijggc.2009.07.003.
Bahadori, A., Vuthaluru, H.B., and Mokhatab, S. 2009. SimpleCorrelation Accurately Predicts Aqueous Solubility of Light Alkanes. EnergySources Part A 31 (9): 761-766. http://dx.doi.org/10.1080/15567030801901570.
Bahadori, A., Vuthaluru, H.B., Tadé, M.O., and Mokhatab, S. 2008.Predicting Water-Hydrocarbon Systems Mutual Solubility. Chem. Eng.Technol. 31 (12): 1743-1747. http://dx.doi.org/10.1002/ceat.200800226.
Barat, R., Montoya, T., Borrás, L., Ferrer, J., and Seco, A. 2008.Interactions between calcium precipitation and the polyphosphate-accumulatingbacteria metabolism. Water Res. 42 (13): 3415-3424. http://dx.doi.org/10.1016/j.watres.2008.05.003.
Bradshaw, J., Bachu, S., Bonijoly, D., et al. 2007. CO2 storage capacityestimation: Issues and development of standards. Int. J. Greenhouse GasControl 1 (1): 62-68. http://dx.doi.org/10.1016/s1750-5836(07)00027-8.
Chilingar, G.V., Mourhatch, R., and Al-Qahtani, G.D. 2008. TheFundamentals of Corrosion and Scaling for Petroleum and EnvironmentalEngineers. Houston, Texas: Gulf Publishing Company. ISBN-10:1-933762-30-6.
Droste, Ronald L. 1997. Theory and Practice of Water and WastewaterTreatment. New York: John Wiley & Sons.
Jones, L.W. 1988. Corrosion and Water Technology for PetroleumProducers, 202. Tulsa, Oklahoma: OGCI Publications.
Langelier, W.G. 1988. The Analytical Control of Anti-Corrosion WaterTreatment. JAWWA 28 (10): 1500-1521.
Liu, X., Jungang, L., Qianya, Z., Jinlai, F., Yingli, L., and Jingxin,S. 2009. The analysis and prediction of scale accumulation for water-injectionpipelines in the Daqing Oilfield. J. Pet. Sci. Eng. 66(3-4): 161-164. http://dx.doi.org/10.1016/j.petrol.2009.02.007.
Matlab®, version 22.214.171.1244. 2008. Natick, Massachusetts: The Mathworks,Inc.
Patton, C.C. 1986. Applied Water Technology. Norman, Oklahoma:Campbell Petroleum Series Inc.
Singurindy, O. and Berkowitz, B. 2005. The role of fractures on coupleddissolution and precipitation patterns in carbonate rocks. Adv. WaterResour. 28 (5): 507-521. http://dx.doi.org/10.1016/j.advwatres.2005.01.002.
Stiff, H.A. Jr. and Davis, L.E. 1952. A Method for Predicting theTendency of Oil Field Waters To Deposit Calcium Carbonate, Vol. 195,SPE-952213-G, 213-216. Dallas, Texas: American Institute of Mining andMetallurgical Engineers Inc. (reprinted 1956).