Compositional Modeling and Calibration of ASP Carbonate Corefloods
- Mohammed T. Al-Muraryi (KOC) | Shawket G. Ghedan (CMG, Now with Dragon Oil Limited) | Fraser Skoreyko (CMG) | Abrahim A. Hassan (KOC) | Ricardo Lara (KOC) | Ali Qubian (KOC)
- Document ID
- Society of Petroleum Engineers
- SPE Middle East Oil and Gas Show and Conference, 18-21 March, Manama, Bahrain
- Publication Date
- Document Type
- Conference Paper
- 2019. Society of Petroleum Engineers
- 1.6 Drilling Operations, 5.4.1 Waterflooding, 2.5.2 Fracturing Materials (Fluids, Proppant), 5 Reservoir Desciption & Dynamics, 5.2 Fluid Characterization, 5.2.1 Phase Behavior and PVT Measurements, 5.4 Improved and Enhanced Recovery, 5.3.4 Reduction of Residual Oil Saturation, 5.8 Unconventional and Complex Reservoirs, 1.6.9 Coring, Fishing, 5.2 Reservoir Fluid Dynamics, 2.6 Acidizing, 5.3.2 Multiphase Flow, 5.3.6 Chemical Flooding Methods (e.g., Polymer, Solvent, Nitrogen, Immiscible CO2, Surfactant, Vapex), 2 Well completion, 5.5.2 Core Analysis, 5.8.7 Carbonate Reservoir, 2.4 Hydraulic Fracturing, 5.5.8 History Matching, 5.4 Improved and Enhanced Recovery, 5.5 Reservoir Simulation, 5.2 Reservoir Fluid Dynamics
- ASP Corefloods, Model Calibration, Carbonate Reservoir, Solubilization Ratio, Micro-Emulsion
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The shortage and high cost of CO2 and/or Hydrocarbon gases, in some areas, makes chemical EOR a practical option for tertiary oil recovery. Alkaline, Surfactant and Polymer, ASP, formulations continue to evolve to withstand challenges in relation to reservoir heterogeneity, complex mineralogy, high temperature and high formation water salinity of carbonate reservoirs. Such advanced ASP formulations have been considered to evaluate the performance of tertiary oil recovery process in a Kuwaiti carbonate reservoir. Successful performance has been seen in the lab through the evaluation of ASP coreflood experiments using composite carbonate cores. This paper presents the results of these coreflooding experiments and the steps followed to build representative ASP flooding simulation models as well as the workflow to calibrate these models to the observed experimental data. Moreover, the paper highlights the challenges associated with ASP coreflooding process and its modeling in the difficult environment of carbonate reservoirs. The paper also presents the techniques followed to overcome some of these challenges.
The modeling of two corefloods are presented in this paper, the first is for high-pressure live oil ASP coreflood, and the second is for low-pressure, surrogate oil ASP coreflood. The carbonate composite cores were first flooded with seawater down to residual oil saturation, Sorw. The ASP coreflood started with pre-flushing phase using softened seawater, followed by an ASP slug, and ended by injecting a number of pore volumes of polymer solution for mobility control. The representative ASP flooding simulation models of this paper captured the vital mechanisms involved in the ASP chemical EOR process, such as:
Micro-emulsion phase behavior, surfactant solubility ratios and resulting IFT changes
Saponification process by the reaction of naphthenic acids of the crude oil with the injected alkali
Adsorption of surfactant and polymer on the carbonate rocks as a function of pH and time
The geochemistry of aqueous and oleic phase reactions
Updating reservoir capillary number, resulting from the changes to IFT and wettability
Effect of changes in capillary number is reflected by different sets of interpolation Kr curves
The rheological behavior of polymer solutions
Optimum salinity and salinity gradient effect.
Assisted history matching software was employed in the calibration of the two corefloods following a stepwise procedure by first matching the water flood results, then matching the surfactant production values, and finally matching the remainder of the ASP flood results. This paper discusses the parameters that needed to be tuned in order to attain a match of both waterflood and ASP flood results. The matched results included the oil recovery, flow pressure differential, and the concentration of chemical effluents traced during the experiments. The profile of ASP oil recovery in these carbonate composite cores is more gradual, and is different from those observed in sandstone corefloods.
|File Size||1 MB||Number of Pages||19|
Farajzadeh, R.,Matsuura, T., van Batenburg, D., and Dijk, D.: "Detailed Modeling of the Alkali/Surfactant/Polymer (ASP) Process by Coupling a Multipurpose Reservoir Simulator to the Chemistry Package PHREEQC", SPE Reservoir Evaluation and Engineering Journal, August 2012, p 423–435. Paper SPE 143671, Presented at the SPE Enhanced Oil Recovery Conference, Kuala Lumpur, Malaysia, 19-21 July, 2011.
Stoll, W.M., al Shureqi, H.,Finol, J.Al-Harthy, S.A.A.,Oyemade, S., de Kruijf, A., van Wunnik, J.,Arkesteijn, F.,Bouwmeester, R., and Faber, M.J.: "Alkaline/Surfactant/Polymer Flood: From Laboratory to the Field", SPE Reservoir Evaluation and Engineering, December 2011. Paper SPE 129164, Presented at the SPE Oil and Gas West Asia Exhibition and Conference, Muscat, Oman, 11-13 April 2010.
Flaaten, A.K.,Nguyen, Q.P.,Pope, G.A.,Zhang, J.: "A Systematic Laboratory Approach to Low-Cost High-Performance Chemical Flooding, Paper SPE 113469, Presented at the Symposium on Improved Oil Recovery, Tulsa, OK, 21-23 April 2008. SPE Reservoir Evaluation & Engineering, 12 (5) 713-723, October, 2009.
Nghiem, L,Skoreyko, F.,Gorucu, S.E.,Dang, C., and Shrivastava, V.: "A Framework for Mechanistic Modeling of Alkali- Surfactant-Polymer Process in an Equation of State Compositional Simulator", Paper SPE 182628, Presented at the SPE Reservoir Simulation Conference, Montgomery, TX, USA, 20-22 February 2017.
Al-Murayri, M.T.,Kamal, D.S.,Sunga, P.,Fortenberry, R.,Britton, C.,Pope, G.A.,Liyanage, P.J.,Jang, S.H.,Upamali, K.: "Improving ASP Performance in Carbonate Reservoir Rocks Using Hybrid-Alkali", Paper SPE 187213, Presented at the SPE Annual Technical Conference and Exhibition, San Antonio, Texas, 9-11 October 2017.
Veedu, F.K.,Smallwood,Nebrigic, D.,Smallwood, A.,Hickey, J., and Wang, P.: "EOR Pilot Design Through an Integrated Laboratory Evaluation and Reservoir Modeling Study for a Large Carbonate Field in Kuwait", Paper SPE 175348, Presented at the SPE Kuwait Oil and Gas Show and Conference, Mishref, Kuwait, 11-14 October 2015.
Carlisele, C.,Al-Maraghi, E.,Al-Saad, B.,Britton, C.,Fortenberry, R.,Pope, G.A.: "One-Spot Pilot Results in the Sabriyah-Mauddud Carbonate Formation in Kuwait Using a Novel Surfactant Formulation", Paper SPE 169153, Presented at the SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, 12-16 April 2014.