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SPE Middle East Health, Safety, Security, and Environment Conference and Exhibition,
2-4 April 2012,
Abu Dhabi, UAE
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Abstract
In recent years, there has been a growing interest in the Gulf Region in Carbon
Capture and Storage (CCS) as well as the use of Carbon Dioxide for Enhance Oil
Recovery (CO2-EOR) in the Middle East Region.
Unlike H2S, carbon dioxide does not support combustion. However, carbon dioxide
can cause asphyxia if inhaled in large quantities. While many Middle Eastern
oil producers have experience with sour oil and gas fields, there is little or
no experience with CCS and CO2-EOR operation.
For CCS and CO2-EOR projects, carbon dioxide is typically transported in
pipelines at pressure above its critical pressure (73.82 bar). In the event of
depressurization or loss of containment, the escaping CO2 will experience a
sudden change in phase which may result in dry ice projectiles being expelled
at very high velocities. Other hazards include cryogenic burns to the skin and
catastrophic failure of carbon steel equipment due to low temperature metal
embitterment.
Dealing with CO2 presents oil producers with new safety challenges. This paper
discusses the safety aspects of handling carbon dioxide in CCS and CO2-EOR
projects.
1. Introduction
According to the International Energy Agency (IEA), the Gulf countries have
some of the highest carbon emissions per capita in the world. In recent years,
there has been a growing interest in the Gulf Region in Carbon Capture and
Storage (CCS) as well as the use of Carbon Dioxide for Enhance Oil Recovery
(CO2-EOR).
The first ever pilot for CO2-EOR in the Middle East was successfully
commissioned and operated by ADCO in Abu Dhabi three years ago (Saadawi 2009).
Abu Dhabi is also investigating capturing CO2 from various industrial sources.
Saudi Aramco announced plans for injection CO2 in the southern part of the
giant Ghawar field. Oil companies in Kuwait and Qatar are investigating the use
of CO2 for EOR applications. While many Middle Eastern oil producers have
experience with sour oil and gas fields, there is little or no experience with
CCS and CO2-EOR operation. Carbon dioxide presents different safety challenges
than hydrogen sulfide
2. Health Hazards of CO2
At room temperature and ambient pressure, CO2 is a colorless, odorless gas
naturally present in the atmosphere in small quantities. However, volcanic
activities can result in large clouds of gases containing CO2 with much large
percentage than available in the atmosphere which are toxic to most forms of
life (FitzGerald 2009). This was evident from the natural disaster that took
place in August 1986 at Lake Nyos in Western Cameron in August 1986. Possibly
as a result of an earth quake or a land slide, a cloudy mixture of carbon
dioxide and water droplets rose violently from the lake. As the lethal cloud
swept the villages down the adjacent valleys, it killed over 1700 people. Most
victims appeared to have simply fallen asleep and died from asphyxiation.
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